Anesthizine is a gas that works as a fast-acting anesthetic drug. In 2379 when members of a rebel Klingon group Klahb attempted to take over the Federation Embassy on Qo'noS, Ambassador Worf was eventually able to subdue them by reactivating the security system and pumping anesthizine gas throughout the building. (TNG novel: A Time for War, A Time for Peace)
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This drug is spelled "Anesthezine" in A Time for War, A Time for Peace. For information about the several different spellings of this drug see the background information in the Anesthizine article at Memory Alpha, the wiki for canon Star Trek.
In 2372, Cantabrian security chief Ulitania Jonar ordered anesthizine to be used to subdue a fighting civilian crowd aboard the Cantabrian. This was effective in control the crowd to be moved to the ship's brig. (Star Trek: The Cantabrian Expeditions: "Isolation")